Directorio

Martín Andrés Iglesias Arteaga
Correo: martin.iglesias@unam.mx
Dr. en Ciencias Químicas
[L] Química Orgánica
[Pg] Introducción a la Química de Esteroides
- Esteroides monoméricos y diméricos
- Esteroides bioactivos
- Sólidos cristalinos
- Catálisis por Oro y Paladio
- Nuevos métodos de síntesis
- RMN
Síntesis de esteroides y dímeros esteroidales. Estudio de sus propiedades biológicas o como Sólidos Cristalinos Funcionales. Reacciones catalizadas por Oro o Paladio. Nuevos métodos sintéticos basados en derivados de yodo polivalente. Caracterización basada en RMN.
- Posgrado en Ciencias Químicas UNAM
- Premio del Consejo Científico del Ministerio de Educación Superior de Cuba Al Resultado Científico De Mayor Trascendencia y Originalidad, 1996.
- Cátedra Patrimonial de Excelencia Nivel II del CONACYt, CINVESTAV, 2001-2003.
- Editor Científico de la Revista Arkivoc, 2005 al presente.
- Miembro del Consejo Editorial de la Revista Natural Products Communications, 2005 al presente.
- Cátedra Patrimonial Jesús Romo Armeria, UAM, 2012.
Santiago‐Sampedro, G. I., Mayorquín‐Torres, M. C., Aguilar‐Granda, A., & Iglesias‐Arteaga, M. A.* (2024). Synthesis and characterization of a highly fluorescent benzofuran dimer derived from estradiol. Journal Of Heterocyclic Chemistry.
DOI:10.1002/jhet.4783
García-Santos, W. H., Flores‐Alamo, M., & Iglesias‐Arteaga, M. A.* (2023). Palladium‐catalyzed synthesis of Benzoannulated spiroketal lactones derived from cholesterol: NMR characterization and crystal structures. Journal Of Heterocyclic Chemistry, 60(12), 2092-2098.
DOI:10.1002/jhet.4739
Ramos-Enrı́Quez, M. A., Vazquez‐Chavez, J., Campos-Xolalpa, N., Pérez-Gutiérrez, S., & Iglesias‐Arteaga, M. A.* (2023). Synthesis, NMR characterization and cytotoxic activity of hybrid spirostanic sapogenins-estradiol dimers. Steroids, 199, 109286.
DOI:10.1016/j.steroids.2023.109286
García-Santos, W. H., Mayorquín-Torres, M. C., Maldonado-Domínguez, M., Medina-Campos, O. N., Pedraza-Chaverri, J., & Iglesias-Arteaga, M. A.* (2023). Mechanistic insights on PD-Catalyzed Three-Component reactions of alkynols, methyl orthoformate, and salicylaldehyde derivatives. Application to the synthesis of steroid chroman ketals and spiroketals with antioxidant activity. The Journal of Organic Chemistry, 88(21), 14860-14873.
DOI:10.1021/acs.joc.3c00857
Franco Cimino, P., Núñez, M., Rosado-Abón, A., Amesty, Á., Estévez-Braun, A., Díaz, K., Espinoza, L.*, & Iglesias-Arteaga, M. A.* (2023). Methyl esters of 23,24-Dinor-5α-cholan-22-oic acids as brassinosteroid Analogues. Synthesis, evaluation of plant growth promoting activity and Molecular docking. Steroids, 196, 109248.
DOI:10.1016/j.steroids.2023.109248
Vazquez-Chavez, J., Martínez-Torres, F. C., Navarro-Huerta, A., Flores-Alamo, M., Maldonado-Domínguez, M., Blahut, J., Štoček, J. R., Dračínský, M., Rodríguez-Molina, B.*, & Iglesias-Arteaga, M. A.* (2023). A Crystalline Dimeric Steroidal Diboronate with Electronically Impeded Rotation. Journal of Organic Chemistry, 88(1), 49-59.
DOI:10.1021/acs.joc.2c01676
García-Santos, W. H., Quiroz-Mendoza, A. M., Mayorquín-Torres, M. C., Flores-Alamos, M., & Iglesias-Arteaga, M. A. (2023). Palladium Catalyzed Synthesis of Benzofuran Spiroketals Derived from Cholesterol. NMR and X-Ray characterization. Synthesis.
DOI:10.1055/a-2093-3333
Ramos-Enríquez, M. A., Medina-Campos, O. N., Pedraza-Chaverri, J., Flores-Álamo, M. & Iglesias-Arteaga, M. A.* (2022). An Unexpected Acid Acid-Catalyzed Rearrangement of Diacetoxy Benzylidenespirostanes to Spirochromene Acetals and Spiroindenes with Radical Scavenger Activity. Steroids, 109110.
DOI:10.1016/j.steroids.2022.109110
Vazquez-Chavez, J., Aguilar-Granda, A. & Iglesias Arteaga, M. A.* (2022). Synthesis and characterization of a fluorescent steroid dimer linked through C-19 by a 1,4-Bis(phenylethynyl)phenylene fragment. Steroids, 187, 109098.
DOI:10.1016/j.steroids.2022.109098
Santiago-Sampedro, G. I., Aguilar-Granda, A., Torres-Huerta, A., Flores-Álamo, M., Maldonado-Domínguez, M.*, Rodríguez-Molina, B.*, & Iglesias-Arteaga, M. A.* (2022). Self-Assembly of an Amphiphilic Bile Acid Dimer: A Combined Experimental and Theoretical Study of Its Medium-Responsive Fluorescence. The Journal of Organic Chemistry, 87(5), 2255–2266.
DOI:10.1021/acs.joc.1c01334
Hernández-Huerta, E., Flores-Álamo, M., & Iglesias-Arteaga, M. A.* (2021). A straightforward one-pot two-step conversion of bile acids into dehomologated alcohols. Steroids, 176.
DOI:10.1016/j.steroids.2021.108917
Ramos-Enríquez, M. A., Romero-Ávila, M., & Iglesias-Arteaga, M. A.* (2021). Reductive desymmetrization of steroid dimers. Steroids, 176, 108918.
DOI:10.1016/j.steroids.2021.108918
Mayorquín-Torres, M. C., Maldonado-Domínguez, M.*, Flores-Álamo, M., & Iglesias-Arteaga, M. A.* (2021). Synthesis and Characterization of Hybrid Dimeric Steroid Spiroketals. Synthesis (Germany).
DOI:10.1055/a-1647-7610
Rosado-Abón, A., & Iglesias-Arteaga, M. A. (2021). Straightforward synthesis of unnatural poly-oxygenated steroid sapogenins. Arkivoc, 2021(10), 18–26.
DOI:10.24820/ark.5550190.p011.596
Mayorquín-Torres, M. C., Navarro-Huerta, A., Maldonado, M., Flores-Álamo, M., Rodríguez-Molina, B., & Iglesias-Arteaga, M. A.* (2021). Palladium-Catalyzed Generation of ortho-Quinone Methides. A Three-Component Synthesis of L-Shaped Dimeric Steroidal Scaffolds. Journal of Organic Chemistry.
DOI:10.1021/acs.joc.0c02943
Ramos-Enrı́quez, M. A., Colin-Molina, A., Flores-Álamo, M., Rodríguez-Molina, B., & Iglesias-Arteaga, M. A. (2020). Phase Transformations of a Conformational Solvatomorphic Steroid: [23(23E,25R]-23(28)-(3′-Acetoxybenzyliden)-5α-spirostan-3β-ol acetate. Crystal Growth & Design, 20(10), 6649-6659.
DOI:10.1021/acs.cgd.0c00808
Mayorquín-Torres, M. C., & Iglesias-Arteaga, M. A. (2020). Application of palladium-catalyzed cross-coupling between bile acids and 2-furanylboronic acid to the synthesis of 24-(2′-furanyl)-24-oxo steroids. Steroids, 162.
DOI:10.1016/j.steroids.2020.108689
Vargas-Romero, K., Martínez-Torres, F. C., Aguilar-Granda, A., Pérez-Estrada, S., Flores-Alamo, M., Rodríguez-Molina, B., & Iglesias-Arteaga, M. A. (2020). Synthesis and Solid-State Dynamics of a Crystalline Steroid Molecular Rotor without the Alkyne Axle: Steroid Dimers Based on a 1,4-Di(1,3-dioxan-2-yl)benzene Moiety. The Journal of Organic Chemistry, 85(13), 8501-8509.
DOI:10.1021/acs.joc.0c00867
Iglesias-Arteaga, M. A., & Hernández-Martínez, J. E. (2020). BF3·OEt2-Catalyzed Aldol Condensation of Steroid Sapogenins and 2-Oxoacids: A Single Step Conversion of Steroid Spiroketals into Branched α,β-Unsaturated Spirolactones. Synthesis.
DOI:10.1055/s-0040-1708018
Serrano-Vázquez, H. A., Flores-Alamo, M., & Iglesias-Arteaga, M. A. (2020). Synthesis of 23E-ethylidene spirostanes via the BF3·Et2O-catalyzed aldol condensation of steroid sapogenins and acetaldehyde. Tetrahedron Letters, 61(22).
DOI:10.1016/j.tetlet.2020.151918
Mayorquín-Torres, M. C., González-Orozco, J. C., Flores-Álamo, M., Camacho-Arroyo, I., & Iglesias-Arteaga, M. A. (2020). Palladium catalyzed synthesis of benzannulated steroid spiroketals. Organic & Biomolecular Chemistry, 18(4), 725-737.
DOI:10.1039/C9OB02255D
Ramos-Enríquez, M. A., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2019). Studies on the reactivity of 23E-benzylidene spirostanes. Steroids, 151.
DOI:10.1016/j.steroids.2019.108462
Mayorquín-Torres, M. C., Santiago-Sampedro, G. I., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2019). Synthesis of symmetrical and hybrid dimeric steroids by double suzuki-miyaura cross coupling of 4-bromo-3-oxo steroids and benzene-1,4-diboronic acid. Synthesis (Germany), 51(15), 2909-2914.
DOI:10.1055/s-0037-1611484
Valdez-García, R. M., Alarcón-Manjarrez, C., Galano, A., Rodríguez-Molina, B., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2019). Synthesis of dimeric steroid trioxabispiroacetals scaffolds by gold(I)-catalyzed Hydroalkoxylation–Hydration of diynediols. European Journal of Organic Chemistry, 2019(30), 4916-4927.
DOI:10.1002/ejoc.201900860
Ramos-Enríquez, M. A., Rárová, L., & Iglesias-Arteaga, M. A. (2018). Synthesis of dimeric spirostanols linked through a 1,4-dimethylidenebenzene moiety by double BF 3 ·Et 2 O-catalyzed aldol condensation of steroid sapogenins and terephtalaldehyde. Steroids, 140, 58-61.
DOI:10.1016/j.steroids.2018.08.005
Mayorquín-Torres, M. C., Colin-Molina, A., Pérez-Estrada, S., Galano, A., Rodríguez-Molina, B., & Iglesias-Arteaga, M. A. (2018). Synthesis, characterization, and solid state dynamic studies of a hydrogen bond-hindered steroidal molecular rotor with a flexible axis. Journal of Organic Chemistry, 83(7), 3768-3779.
DOI:10.1021/acs.joc.8b00134
Valdez-García, R. M., Alarcón-Manjarrez, C., Arcos-Ramos, R., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2018). Synthesis and characterization of dimeric steroids based on 5-oxo-4,5-seco-yne units linked by a diyne spacer. Arkivoc, 2018(4), 13-22.
DOI:10.24820/ark.5550190.p010.459
Ramos-Enríquez, M. A., & Iglesias-Arteaga, M. A. (2017). Synthesis of novel hybrid steroid dimers by BF3·Et2O-catalyzed aldol condensation of 2-formyl-estradiol diacetate and steroid sapogenins. Steroids, 128, 46-49.
DOI:10.1016/j.steroids.2017.10.008
Vargas-Romero, K., Alberto, O., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2017). Baeyer-villiger reaction of steroid sapogenins by CF3COOH-H2O2. A short cut to pregnan-3β,16β,20-triol 3-monoacetates. Steroids, 128, 1-5.
DOI:10.1016/j.steroids.2017.10.001
Ramos-Enríquez, M. A., Vargas-Romero, K., Rárová, L., Strnad, M., & Iglesias-Arteaga, M. A. (2017). Synthesis and in vitro anticancer activity of 23(23′)E-benzylidenespirostanols derived from steroid sapogenins. Steroids, 128, 85-88.
DOI:10.1016/j.steroids.2017.08.017
Mayorquín-Torres, M. C., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2017). An unexpected course of a palladium catalyzed three-component reaction leading to steroid chroman ketals. Tetrahedron Letters, 58(36), 3500-3504.
DOI:10.1016/j.tetlet.2017.07.081
Mayorquín-Torres, M. C., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2017). Synthesis of benzannulated steroid spiroketals by palladium-catalyzed spirocyclization of steroid alkynediols. Tetrahedron Letters, 58(21), 2073-2076.
DOI:10.1016/j.tetlet.2017.04.051
Ramos Enríquez, M. A., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2016). An unexpected BF3·Et2O-catalyzed rearrangement of 23E-benzylidenespirostanes to spiro[furan-indenes]. Tetrahedron Letters, 57(21), 2249-2252.
DOI:10.1016/j.tetlet.2016.04.032
Alarcón-Manjarrez, C., Arcos-Ramos, R., Álamo, M. F., & Iglesias-Arteaga, M. A. (2016). Synthesis, NMR and crystal characterization of dimeric terephthalates derived from epimeric 4,5-seco-cholest-3-yn-5-ols. Steroids, 109, 66-72.
DOI:10.1016/j.steroids.2016.03.001
Alarcón-Manjarrez, C., Vargas-Romero, K., González-Cruz, T. L., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2016). The crystal structures of the α- and β-diastereomers of 4,5-epoxy-cholestan-3-one. Journal of Chemical Crystallography, 46(3), 155-161.
DOI:10.1007/s10870-016-0639-x
Viviano-Posadas, A. O., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2016). Regioselective hypervalent iodine-induced favorskii rearrangement of 3-oxo-5β-steroids. Steroids, 113, 22-28.
DOI:10.1016/j.steroids.2016.06.003
Mayorquín-Torres, M. C., Arcos-Ramos, R., Flores-Álamo, M., & Iglesias-Arteaga, M. A. (2016). Crystalline arrays of side chain modified bile acids derivatives. two novel self-assemblies based on π-π and belly-to-belly interactions. Steroids, 115, 169-176.
DOI:10.1016/j.steroids.2016.09.007