Directorio

Juventino García Alejandre
Correo: juvent@unam.mx
Quimico, 1985, Facultad de Química. UNAM. Graduado con Mención Honorífica.
M en C., 1988, Facultad de Química. UNAM. Medalla Gabino Barreda al mérito universitario.
Doctorado, 1991, Facultad de Química. UNAM. Medalla Gabino Barreda al mérito universitario.
Post Doc. (1992-1993), University of Sheffield, UK.
Sabático (1999-2000), University of Rochester, NY. USA.
Quimica de Coordinación
Química Organometálica
Síntesis Orgánica Mediada por Metales
Catálisis Homogénea
Temas Selectos de Química Inorgánica
- Química organometálica
- Química de coordinación con elementos del bloque D
- Catálisis homogénea
- Nanocatálisis
- Química verde
- Síntesis orgánica mediada por metales
- Química organometálica
- Química de coordinación con elementos del bloque d
- Catálisis homogénea
- Nanocatálisis
- Química verde
- Síntesis orgánica mediada por metales
- Programa de Maestría y Doctorado en Ciencias Químicas
- Mención Honorifica en Licenciatura (1985)
- Medalla de plata Gabino Barreda en Maestría (1988)
- Medalla de Plata Gabino Barreda en Doctorado (1993)
- Becario postdoctoral Pierre y Marie Curie por la Unión Europea(1992-1993)
- Becario Sabático Fulbright-García Robles (1999-2000)
- Distinción Universidad Nacional a Jovenes Académicos (2000)
- PRIDE D
- Miembro del Sistema Nacional de investigadores Nivel 3
- Premio Nacional de Química “Andrés Manuel del Rio” 2010, área académica de docencia
García-Ventura, I., Roa, D. A., & Garcı́a, J. J.* (2024). Oxidative metal-free C–C bond activation of a β−β lignin model compound by H2O2/HCOOH system. Tetrahedron, 151, 133808.
DOI:10.1016/j.tet.2023.133808
Torres-Calis, A., Roa, D. A., & Garcı́a, J. J.* (2023). Homogeneous manganese-catalyzed hydroamination of alkenes via the reductive coupling with nitroarenes. Journal Of Catalysis, 427, 115097.
DOI:10.1016/j.jcat.2023.115097
Peñuelas, C. A., Campos‐Gaxiola, J. J.*, Soto-Rojo, R., Cruz‐Enríquez, A., Reynoso‐Soto, E. A., Miranda‐Soto, V., Garcı́a, J. J., Flores-Álamo, M., Baldenebro-López, J., & Glossman‐Mitnik, D. (2023). Synthesis of a New Dinuclear Cu(I) Complex with a Triazine Ligand and Diphenylphosphine Methane: X-ray Structure, Optical Properties, DFT Calculations, and Application in DSSCs. Inorganics (Basel), 11(10), 379.
DOI:10.3390/inorganics11100379
Chavez-Urias, I. F., López-González, L. E., Plascencia-Martínez, D. F., Garcı́a, J. J., Flores-Álamo, M., Sugich-Miranda, R., Medrano, F., Picos-Corrales, L. A., López-Gastélum, K.*, Velázquez-Contreras, E. F.*, & Rocha-Alonzo, F.* (2023). l-Isoleucine-Schiff Base Copper(II) Coordination Polymers: Crystal Structure, Spectroscopic, Hirshfeld Surface, and DFT Analyses. ACS Omega, 8(27), 24601-24614.
DOI:10.1021/acsomega.3c02878
Zanchet, D.*, García, J. J.*, & Baldovino Medrano, V. G.* (2023). Catalysis in latin america. ChemCatChem, 15(8).
DOI:10.1002/cctc.202201577
Roa, D. A., & Garcia, J. J.* (2023). Hydrosilylation and electroreduction of CO2 using a zirconocene hydride catalyst. New Journal of Chemistry, 47(9), 4504-4509.
DOI:10.1039/d2nj06204f
Lama, I. M. F., Roa, D. A., Arévalo, A., & García, J. J.* (2023). Additive-free reductive hydrodeoxygenation of fatty acids catalyzed by inexpensive simple nickel(II) compounds. New Journal of Chemistry.
DOI:10.1039/d3nj01001e
Torres-Calis, A., & García, J. J.* (2022). Homogeneous manganese-catalyzed hydrofunctionalizations of alkenes and alkynes: Catalytic and mechanistic tendencies. ACS Omega, 7(42), 37008-37038.
DOI:10.1021/acsomega.2c05109
Roa, D. A. & Garcia, J. J.* (2022). Hydrogenation of levulinic acid to γ-valerolactone using a homogeneous titanium catalyst at mild conditions. Journal of Catalysis, 413, 1028-1033.
DOI:10.1016/j.jcat.2022.08.013
Soto-Acosta, S., Campos-Gaxiola, J. J.*, Reynoso-Soto, E. A., Cruz-Enríquez, A., Baldenebro-López, J., Höpfl, H., García, J. J., Flores-Álamo, M., Miranda-Soto, V. & Glossman-Mitnik, D. (2022). Synthesis, Crystal Structure, DFT Studies and Optical/Electrochemical Properties of Two Novel Heteroleptic Copper(I) Complexes and Application in DSSC. Crystals, 12(9), 1240.
DOI:10.3390/cryst12091240
Jurado‐Vázquez, T., Rosaldo, E., Arévalo, A. & García, J. J.* (2022). Levulinic Acid Hydrogenation with Homogeneous Cu(I) Catalyst. ChemCatChem.
DOI:10.1002/cctc.202200628
Torres-Calis, A. & García, J. J.* (2022). Manganese-catalyzed transfer semihydrogenation of internal alkynes to E-alkenes with iPrOH as hydrogen source. Catalysis Science & Technology, 12(9), 3004-3015.
DOI:10.1039/d2cy00246a
Robles-Marín, E., Flores-Alamo, M., & Garcia, J. J.* (2022). Electrochemical activation of CO2 by MOF-(Fe, Ni, Mn) derivatives of 5-aminoisophthalic acid and the thiazole group influence on its catalytic activity. New Journal of Chemistry, 46(13), 6060-6067.
DOI:10.1039/d2nj00364c
Jurado-Vázquez, T., Arévalo, A., & García, J. J.* (2022). Furfural and 5-(hydroxymethyl)furfural valorization using homogeneous Ni(0) and Ni(II) catalysts by transfer hydrogenation. Journal of Organometallic Chemistry, 957, 122162.
DOI:10.1016/j.jorganchem.2021.122162
López-Gastélum, K. A.*, Velázquez-Contreras, E. F.*, García, J. J., Flores-Alamo, M., Aguirre, G., Chávez-Velasco, D., Narayanan, J., & Rocha-Alonzo, F*. (2021). Mononuclear and Tetranuclear Copper(II) Complexes Bearing Amino Acid Schiff Base Ligands: Structural Characterization and Catalytic Applications. Molecules, 26(23), 7301.
DOI:10.3390/molecules26237301
Jurado-Vázquez, T., Arévalo, A., & García, J. J.* (2021). Furfural and 5-(hydroxymethyl)furfural valorization using homogeneous Ni(0) and Ni(II) catalysts by transfer hydrogenation. Journal of Organometallic Chemistry, 122162.
DOI:10.1016/j.jorganchem.2021.122162
González, T., & García, J. J. (2021). Catalytic CO2 hydrosilylation with [Mn(CO)5Br] under mild reaction conditions. Polyhedron, 203.
DOI:10.1016/j.poly.2021.115242
Jurado-Vázquez, T., Arévalo, A., & García, J. J.* (2021). Transfer Hydrogenation of Levulinic Acid to γ‐Valerolactone and Pyrrolidones Using a Homogeneous Nickel Catalyst. European Journal of Inorganic Chemistry, 2021(5), 445-450.
DOI:10.1002/ejic.202001063
Roa, D. A., & Garcia, J. J.* (2021). Mild reduction with silanes and reductive amination of levulinic acid using a simple manganese catalyst. Inorganica Chimica Acta, 516.
DOI:10.1016/j.ica.2020.120167
Garduño, J. A., & Garcia, J. J. (2020). Toward Amines, Imines, and Imidazoles: A Viewpoint on the 3d Transition Metal-Catalyzed Homogeneous Hydrogenation of Nitriles. ACS Catalysis.
DOI:10.1021/acscatal.0c02283
Flores-Alamo, M., Perez-Ortiz, F. J., Arevalo, A., & Garcia, J. J. (2020). [1,2-Bis(diisopropylphosphanyl)ethane-κ2 P,P′](2-fluoro-N-{[(2-fluorophenyl)azanidyl]carbonyl}anilinido-κ2 N,N′)nickel(II). IUCrData, 5(5).
DOI:10.1107/s2414314620006495
Rodríguez, A. A., Garduño, J. A., & García, J. J. (2020). Nickel(ii) and nickel(0) complexes as precursors of nickel nanoparticles for the catalytic hydrogenation of benzonitrile. New Journal of Chemistry, 44(3), 1082-1089.
DOI:10.1039/c9nj05221f
Esquer, R., & García, J. J. (2019). Metal-catalysed Poly(Ethylene) terephthalate and polyurethane degradations by glycolysis. Journal of Organometallic Chemistry, 902.
DOI:10.1016/j.jorganchem.2019.120972
Garduño, J. A., Flores-Alamo, M., & García, J. J. (2019). Manganese‐Catalyzed Transfer Hydrogenation of Nitriles with 2‐Butanol as the Hydrogen Source. ChemCatChem, 11(21), 5330-5338.
DOI:10.1002/cctc.201901154
Benitez-Medina, G. E., & García, J. J. (2019). Hydrogenation and N-alkylation of anilines and imines via transfer hydrogenation with homogeneous nickel compounds. Dalton Transactions, 48(47), 17579-17587.
DOI:10.1039/c9dt04111g
Islas, R. E., & García, J. J. (2019). Nickel-catalyzed hydrophosphonylation and hydrogenation of aromatic nitriles assisted by lewis acid. ChemCatChem, 11(4), 1337-1345.
DOI:10.1002/cctc.201801989
Garduño, J. A., & García, J. J. (2019). Non-pincer mn(I) organometallics for the selective catalytic hydrogenation of nitriles to primary amines. ACS Catalysis, 9(1), 392-401.
DOI:10.1021/acscatal.8b03899
Facundo, A. A., Arévalo, A., Fundora-Galano, G., Flores-Álamo, M., Orgaz, E., & García, J. J. (2019). Hydrodefluorination of functionalized fluoroaromatics with triethylphosphine: A theoretical and experimental study. New Journal of Chemistry, 43(18), 6897-6908.
DOI:10.1039/c9nj00721k
Gutiérrez-Ordaz, R., & García, J. J. (2018). Desulfurization of dibenzothiophene and dibenzothiophene sulfone via Suzuki–Miyaura type reaction: Direct access to o-terphenyls and polyphenyl derivatives. Polyhedron, 154, 373-381.
DOI:10.1016/j.poly.2018.08.008
Jurado-Vázquez, T., & García, J. J. (2018). Iron catalyzed CO2 activation with organosilanes. Catalysis Letters, 148(4), 1162-1168.
DOI:10.1007/s10562-018-2305-8
Garduño, J. A., Arévalo, A., Flores-Alamo, M., & García, J. J. (2018). Mn(i) organometallics containing the iPr2P(CH2)2PiPr2 ligand for the catalytic hydration of aromatic nitriles. Catalysis Science and Technology, 8(10), 2606-2616.
DOI:10.1039/c8cy00416a
Islas, R. E., & García, J. J. (2017). Hydrophosphonylation of alkynes with trialkyl phosphites catalyzed by nickel. ChemCatChem, 9(21), 4125-4131.
DOI:10.1002/cctc.201700974
Correa-Ayala, E., Campos-Alvarado, C., Chávez, D., Morales-Morales, D., Hernández-Ortega, S., García, J. J., Flores-Álamo, M., Miranda-Soto, V., & Parra-Hake, M. (2017). Ruthenium II (p-cymene) complexes bearing ligands of the type 1-[2′-(methoxycarbonyl)phenyl]-3-[4′-X-phenyl]triazenide (X = F, cl, br, I): Synthesis, structure and catalytic activity. Inorganica Chimica Acta, 466, 510-519.
DOI:10.1016/j.ica.2017.06.064
Garduno, J. A., & García, J. J. (2017). Nickel-catalyzed transfer hydrogenation of benzonitriles with 2-propanol and 1,4-butanediol as the hydrogen source. ACS Omega, 2(5), 2337-2343.
DOI:10.1021/acsomega.7b00545
Castellanos-Blanco, N., Flores-Alamo, M., & García, J. J. (2017). Nickel-catalyzed reduction of ketones with water and triethylsilane. Inorganica Chimica Acta, 466, 324-332.
DOI:10.1016/j.ica.2017.06.035
García, J. J., Pérez-Lezama, N., & Arévalo, A. (2017). Hydrogenation of heteroaromatic nitriles and aromatic dinitriles by heterogeneous or homogeneous ruthenium catalysts derived from [Ru3(CO)12]. Inorganica Chimica Acta, 464, 55-58.
DOI:10.1016/j.ica.2017.04.051
Oliveros-Cruz, S., Arévalo, A., & García, J. J. (2017). Synthesis of α-pyrones by catalytic oxidative coupling of terminal alkynes and carbon dioxide. Journal of Organometallic Chemistry, 831, 18-22.
DOI:10.1016/j.jorganchem.2016.12.033
Correa-Ayala, E., Valle-Delgado, A., Ríos-Moreno, G., Chávez, D., Morales-Morales, D., Hernández-Ortega, S., García, J. J., Flores-Álamo, M., Miranda-Soto, V., & Parra-Hake, M. (2016). Synthesis, structures and catalytic activity of 1,3-bis(aryl)triazenide(p-cymene)ruthenium(II) complexes. Inorganica Chimica Acta, 446, 161-168.
DOI:10.1016/j.ica.2016.03.004
Ortiz-Cervantes, C., Flores-Alamo, M., & García, J. J. (2016). Synthesis of pyrrolidones and quinolines from the known biomass feedstock levulinic acid and amines. Tetrahedron Letters, 57(7), 766-771.
DOI:10.1016/j.tetlet.2016.01.018
García-Ventura, I., Flores-Alamo, M., & García, J. J. (2016). Carbon-carbon vs. carbon-oxygen bond activation in 2- and 3-furonitriles with nickel. RSC Advances, 6(103), 101259-101266.
DOI:10.1039/c6ra20244f
Jurado-Vázquez, T., Ortiz-Cervantes, C., & García, J. J. (2016). Catalytic reduction of CO2 with organo-silanes using [Ru3(CO)12]. Journal of Organometallic Chemistry, 823, 8-13.
DOI:10.1016/j.jorganchem.2016.08.032
Castellanos-Blanco, N., Arévalo, A., & García, J. J. (2016). Nickel-catalyzed transfer hydrogenation of ketones using ethanol as a solvent and a hydrogen donor. Dalton Transactions, 45(34), 13604-13614.
DOI:10.1039/c6dt02725c
Zurita, D. A., Flores-Alamo, M., & García, J. J. (2016). Catalytic transfer hydrogenation of azobenzene by low-valent nickel complexes: A route to 1,2-disubstituted benzimidazoles and 2,4,5-trisubstituted imidazolines. Dalton Transactions, 45(25), 10389-10401.
DOI:10.1039/c6dt01674j